First of all you must download MikTex2.9 and an editor.I prefer Texmaker.After installation success go to configure Texmaker.

  1. Options⇒Configure Texmaker⇒Commands⇒Latex type latex -interaction=nonstopmode %.tex
  2. Options⇒Configure Texmaker⇒Commands⇒PdfLatex type xelatex -interaction=nonstopmode %.tex
  3. Options⇒Configure Texmaker⇒Commands⇒PdfViewer check External Viewer and browse to your PdfReader
  4. Options⇒Configure Texmaker⇒QuickBuild check PdfLatex + ViewPDF
  5. Options⇒Configure Texmaker⇒Editor choose UTF-8 encoding

Go to MikTex2.9 options and packages.From Start⇒Programs⇒MikTex2.9⇒Maintenance choose Settings and check if greek language is selected.Then choose Package Manager and install xetex packages.Now open TexMaker and type: 

\documentclass[12pt,a4paper]
\usepackage{fontspec}
\usepackage{xunicode}
\usepackage{xltxtra}
\usepackage{xgreek}
\setmainfont[Mapping=TeX-text]{Times New Roman}
\usepackage{graphicx}
\usepackage[scale=0.8]{geometry}
\usepackage[acronym]{glossaries}

For those who want to create a professional cv with Latex i recommend moderncv template and this link.
An important issue which i realized is that if you want to add greek font in a moderncv template there is a problem with upper-lower case letters.It recognizes only capital letters and ignores lowercase so you must play with \newcommands in order to modify your text.I added this line below above code and it worked for me:

\newcommand{\txt}[1]{\textrm{#1}}

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